SAFETY DATA SHEET ADH9 EVO-STIK 3019
1. IDENTIFICATION OF THE PREPARATION AND THE COMPANY
Product Name:
|
EVO-STIK 3019 |
Product Code:
|
455919 |
Supplier: Sheppy Limited
Rushenden Road
Queenborough
Kent
ME11 5HH
Telephone No: (01795) 580181
Fax No: (01795) 580649
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient Name
|
EC No.
|
CAS No.
|
Content
|
Classification
|
|
Bisphenol A-Epichlorohydrin Epoxy Resin (Number AV MW<700) |
500-033-5 |
25068-38-6 |
<1% |
Xi;R36/38. N,R51/53. R43 |
|
Butanone |
201-159-0 |
78-93-3 |
60-100% |
F;R11 Xi;R36 R66 R67 |
|
Cyclohexanone |
203-631-1 |
108-94-1 |
1-5% |
R10
Xn; R20 |
|
Ethanol |
200-578-6 |
64-17-5 |
<1% |
F;R11 |
|
Tetrahydrofuran |
203-726-8 |
109-99-9 |
5-10% |
Xi; R36/37.
F:R11. R19 |
| (The full Text for All R-Phrases are Displayed in
Section 16) |
3. HAZARDS IDENTIFICATION
Highly flammable. Repeated exposure may cause skin
dryness or cracking. Vapours may cause drowsiness and
dizziness. Irritating to eyes.
Vapours are heavier than air and can travel long
distances to a source of ignition. Pilot lights can
ignite the vapour.
CLASSIFICATION: Xi: R36. F;R11. R66. R67.
4. FIRST AID MEASURES
Inhalation: Remove victim immediately from source of
exposure. Move the exposed person to fresh air at once.
Get medical attention.
Ingestion: DO NOT induce vomiting. Get medical attention
immediately.
Skin Contact: Promptly flush contaminated skin with
water. Promptly remove clothing if soaked through and
flush the skin with water. Wash skin with soap and
water. Get medical attention if irritation perisists
after washing.
Eye Contact: Rinse the eye with water immediately.
Continue to rinse for at least 15 minutes and get
medical attention..
5. FIRE FIGHTING MEASURES
Extinguishing Media: Fire can be extinguished using:
Powder, Foam.
Unusal Fire & Explosion Hazards: Generates massive
smoke during fire. Vapours are heavier than air and may
spread near ground to sources of ignition. HIGHLY
INFLAMMABLE! Risk of explosion in closed containers if
pressure rises rapidly. Solvent vapours may form
exlosive mixtures with air.
Specific Hazards: Toxic gases/vapours/fumes of Carbon
dioxide (CO2). Carbon monoxide(CO).
Protective measure in fire: Wear self contained
breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Avoid skin and eye contact.
Ensure adequate ventilation. Wear personal protective
equipment
Environmental precautions: Prevent entry into drains and
water courses.
Spill Clean-Up Methods: Extinguish all ignition sources.
Avoid sparks, flames, heat and smoking. Ventilate. Run-off
or release to sewer, waterway or ground is
forbidden. Absorb onto sand, earth or absorbent
granules. Pick up with non-sparking tools and place into
metal containers with seal able lids. Mark containers
with details of hazards and store in designated area
ready for disposal.
7. HANDLING AND STORAGE
Usages Precautions: Keep away from heat, sparks and
open flame. Avoid spilling, skin and eye contact.
Ventilate well, avoid breathing vapours. Use approved
respirator if air contamination is above accepted level.
Storage Precautions: Flammable/combustible - Keep away
from oxidisers, heat and flames. Ground container and
transfer equipment to eliminate static electric sparks.
Store at moderate temperature in dry, well ventilated
area.
Storage Class: Flammable liquid storage.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Ingredient Name
|
STD.
|
LT - ppm
|
LT - mg/m3
|
ST ppm
|
ST -
mg/m3
|
|
Ethanol |
WEL |
1000 ppm |
1920 mg/m3 |
|
|
|
Butanone |
WEL |
200 ppm (Sk) |
600
mg/m3 (Sk) |
300
ppm (Sk) |
899
mg/m3 (Sk) |
|
Cyclohexanone |
WEL |
10
ppm (Sk) |
|
20
ppm (Sk) |
|
|
Tetrahydrofuran |
WEL |
50 ppm(Sk) |
|
100 ppm(Sk) |
|
Protective Equipment
Engineering Measures: Explosion-proof general and
local exhaust ventilation.
Respiratory Equipment: Respiratory protection must be
used if air contamination exceeds acceptable level. Wear
mask supplied with gas cartridge suitable for organic
substances.
Hand Protection: Protective gloves must be used if there
is a risk of direct contact or splash. Use protective
gloves made of Nitrile. Use thin cotton gloves inside
the rubber gloves if allergy risk.
Eye Protection: Wear splash-proof eye goggles to prevent
any possibility of eye contact.
Other Protection: Wear appropriate clothing to prevent
repated or prolonged skin contact.
Hygiene Measures: DO NOT SMOKE IN WORK AREA! Wash
promptly if skin becomes contaminated. Wash at the end
of each work shift and before eating, smoking and using
the toilet. Use appropriate skin cream to prevent drying
of skin.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Thixotropic Liquid
Colour: Colourless
Odour: Organic solvents.
Boiling Point (oC) 65 760 mm Hg Relative Density: 0.9 @
20 oC
Flash Point (oC) minus 14CC (Closed cup)
10. STABILITY AND REACTIVITY
Stability: Avoid heat, sparks, flames.
Materials to avoid: Strong oxidising substances.
Hazardous Decomposition Products: Fire or high
temperatures create: Toxic gase/vapours.fumes of Carbon
Dioxide(CO2) and Carbon Monoxide (CO).
11. TOXICOLOGICAL INFORMATION
Inhalation: Drowsiness, dizziness, disorientation,
vertigo. Gas or vapour may irritate respiratory system.
Ingestion: Pneumonia may be the result if vomited
material containing solvents reaches the lungs.
Skin contact: Prolonged contact may cause dryness of the
skin. May cause skin irritation/eczema.
Eye contact: Irritating to eyes. Irritation, burning,
lachrymation, blurred vision after liquid splash.
Health warnings: Defats the skin. Prolonged or repeated
exposure may cause severe irritation.
Medical considerations: Skin disorders and allergies.
12. ECOLOGICAL INFORMATION
Ecotoxicity: Not regarded as dangerous for the
environment. However, contamination of the aquatic or
terrestrial environments should be avoided.
13. DISPOSAL CONSIDERATION
General Information: This material is classified as
special waste as defined by Special Waste Regulations
1996 and must be disposed of by an authorised
contractor.
Disposal Methods: Dispose of waste and residues in
accordance with local authority requirements. Do not
allow runoff to sewer, waterway or ground. Recover and
reclaim or recycle, if practical.
Waste Class: Classifed as Special Waste. Not permitted
for landfill in liquid state.
14. TRANSPORT INFORMATION
| UK ROAD CLASS |
3 |
PROPER SHIPPING NAME: |
ADHESIVES |
|
UN NO. ROAD |
1133 |
UK ROAD PACK GR. |
III |
|
ADR CLASS NO. |
3 |
ADR CLASS |
Class 3: Flammable liquids |
|
ADR PACK GROUP |
III |
HAZARD NO. (ADR) |
30 |
|
ADR LABEL NO. |
3 |
HAZCHEM CODE |
3Y |
|
CEFIC TEC(R) NO. |
30GF1-III,30GF1-sp |
RID CLASS NO. |
3 |
|
RID PACK GROUP |
III |
UN NO. SEA |
1133 |
|
IMDG CLASS |
3 |
EMS |
F-E, S-D |
|
MFAG |
See Guide |
MARINE POLLUTANT |
No. |
|
UN NO. AIR |
1133 |
AIR CLASS |
3 |
|
AIR PACK GR. |
III |
|
|
15. REGULATORY INFORMATION
Label for Supply:
|
Irritant Highly |
Flammable |
| Risk Phrases: |
R11 |
Highly flammable |
| |
R36 |
Irritating to eyes |
|
R66 |
Repeated exposure may cause skin dryness or cracking |
|
R67 |
Vapours may cause drowsiness and dizziness |
|
Safety Phrases: |
S2 |
Keep out of the reach of children |
| |
S9 |
Keep container in a well ventiliated place |
|
S16 |
Keep away from sources of iginition - No smoking |
|
S26 |
In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice. |
|
S36/37/39 |
Wear suitable protective clothing, gloves and
eye/face protection. |
|
S46 |
If swallowed, seek medical advice immediately and
show this container or label. |
|
S51 |
Use only in well-ventiliated areas. |
|
S56 |
Dispose of this material and its container to
hazardous or special waste collection point |
|
P5 |
Contains expoxy constituents. See information
supplied by the manufacturer. |
|
P14 |
Contains Bisphenol A-Epichlorohydrin Epoxy Resin
(Number AV MW<700). May produce an allergic reaction. |
STATUTORY INSTRUMENTS
Chemicals (Hazard Information and Packaging)
Regulations. Control of Substances Hazardous to Health.
APPROVED CODE OF PRACTICE
Classification and Labelling of Substances and
Preparations Dangerous for Supply.
GUIDANCE NOTES
Workplace Exposure Limits EH40, CHIP for everyone
HSG(108). Introduction to Local Exhaust Ventililation
HS(G)37
16. OTHER INFORMATION
Information Sources: This safety data sheet was
complied using current safety information supplied by
distributor of raw materials.
Revision Comments: This safety data sheet supersedes all
previous issues and users are cautioned to ensure that
it is current. Destroy all previous data sheets and if
in doubt contact Sheppy Limited.
Risk Phrases in Full:
R10 Flammable.
R11 Highly flammable.
R19 May form explosive peroxides.
R20 Harmful by inhalation.
R36 Irritating to eyes.
R36/37 Irritating to eyes and respiratory system.
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R66 Repeated exposure may cause skin dryness or
cracking.
R67 Vapours may cause drowsiness and dizziness.
REF: LEAFLET CHIPS/ADH9 ISSUE 1 -November 2005
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